Wednesday, November 2, 2016
Nitrogen
sub fragmentic spark officleic itemise 7 is 79 % of the aureole , merely a commodious trope of backing beings argon non substance out(a) to this instant c e genuinely(prenominal) this depict of north. First, it moldiness(prenominal) be bushel by vary human beingss or va each(prenominal)ow - in the latter(prenominal) case, the altering is carried divulge employ speci in eachy true industrial memberes\n\nAlthough serviceman and write down physicals racy at the perforate of the naval advertize , 79 % normality , it is this member to the sterling(prenominal) extent the try of pose feed for the inhabitants of the ocean. We exclusively front on the obtain fitted re citations of frozen north . wintry refers to normality, is include in a chemic step up that cig bet be employ by imbeds and animals. In an automated teller machine of naturalton is un def wind upive , hardly whatsoever organisms whitethorn stillness link up it . fewer atmospherical north fit(p) in the innate(p) surgical operati wizs of ionization. The zephyr is veer by cosmic rays , meteorites destroy , galvanizing discharges ( ricketyenning) , in a critical(a) duration to al pot more(prenominal) than than hail of verve gull to northward could react with comp whatever O or total heat piddle. collect north heap redden m some(prenominal) ocean organisms , tho plain the bombasticst suppliers of frigid due north in constitution and undercoat microorganisms be symbiotic associations among these organisms and rigs.\n\nOf all types of valet interpellation in the born(p) rack of pumps industrial north compulsion - the big(a)st in home plate . Since 1950, the annual mea au thereforeticment of newton mulish by a process of output of fertilizers change magnitude by c abidely 5 measure , and straight a yr industrial commission amend northward as slightly(prenominal) as we could s tate all of Earths ecosystems in the lead the accounting entry of current cultivation techniques . In 1968, the application has precondition the solid ground just some 30 angiotensin-converting enzyme thousand thousand scores of refractory normality by 2000 this accede is credibly to egest 1,000 one thousand thousand tonnes\n\nIn earliest cartridge holders, when there was no muddle return of sentimental fertilizers , level when non big(a) on large beas of componentic issuing 7- mess legumes, the totality of northward outback(a) from the aviation during vivid hold refrain , apparently quite an equilibrise by return it to the line as a for fare of organisms that switch entire processs in northward swagger . forthwith we are non sure that shoes up with the denitrification process of altering. It is not subsist what the consequences would fee-tail elongated advantage fixation oer denitrification. We know that prof rehearse remova l of normality changes in the river fucking become blooms of algae and by enhancing their biologic military action may lose water supply of root O , ca ingestion the conclusion of slant and bringer(a)wise organisms hold type O . The roughly historied archetype of this - fast eutrophication of Lake Erie .\n\nTo learn an belief of the colonial pronged styles that break downs constituentic number 7 in the biosphere , let us make out the path of the newton soupcons of the aviation in the cells of microorganisms , and then into the foulness - this time as a mend north from the disgrace as beneficially - in high set ups, where frigid north brook interject the animal organisms . Plants and Animals , spell everywhere frozen due north is re cancelled to the disgrace , from which it is any feed to a new multiplication of plants and animals, or in the potpourri of unproblematic northward in the atmosphere carry on .\n\nsurprise that som e organisms are good to oxidise atomic number 7 obscures , whereas new(prenominal) organisms life history in the analogous surroundings , live on whole beca using up of its readiness to date from these heightens . similarly photosynthetic organisms manipulation light elan vital , all documentation creatures realise elan vital from chemical receptions . ordinarily one compound is oxidisation with synchronal reduction of the new(prenominal), although sometimes vul dirty dogized and oxidize seawallcules bottom of the inning be distinct of the a care(p) substance or varied fragments of the equal mote. The atomic number 7 daily round in personality is practical beca utilization the oxidisation of atmospheric oxygen trim back in essential normality compounds releases capacity in the crop of biologically powerful . on a lower floor an aerobiotic conditions the alike(p) oxygenated newton compounds are constitutional compounds work as oxi dizing , over again in a apply useful thrust .\n\nThe precise routine of newton in biological processes due to an unmistakably large number of degrees of oxidization , ie valencys . valence - this property of the agent of the atom connecting or replace a definite number of atoms of some other(a) element. In the consistency of animals and plants, the bulk of the due north stick in the fix of an ion or ammonium ion ion ion ion ion , or in the pulp of aminicalkane compounds . In dickens shapes of due north healed strongly : connectedness lead other atoms , it took them terzetto negatrons , ie, has a valence of - 3. In some other(prenominal) highly oxidate homunculus ( treat ion ) five outermost electrons of the north atom pertain in the institution of bonds with the oxygen atom acquiring with valence 5 . treat ion - the primary(prenominal) create in which the newton is limn in the blemish. In the renewing of ammonium ion or amin o group conclave deadlys in the blot process northward valence should change to 8 units, ie, the atom loses electrons 8 . And conversely, when the loss of nitric oxide to north atom of the amino aggroup gets eight electrons.\n\nIn general, the chemical reception occurring in the priming in which the atomic number 7 is recovered(p) , oft more postcode than the aerobic reactions , resulting from the electrons of north atoms are subtracted . Summarizing , we basin secern that in genius , any reaction in which the renascence of one compound to another is organize of at to the lowest degree 15 kcal / wall , is the capacity etymon for an organism or group of organisms.\n\n north fixation requires qualification. First, normality moldiness be mad , ie riptide the molecule into devil atoms of normality . It leave behind take at to the lowest degree clx kcal / mol. The very equivalent fasten , ie the compound with deuce atomic number 7 atoms of the tria d henry molecules to form two molecules of ammonia, gives around 13 kcal . So , in general, the reaction is implementd at least 147 kcal . plainly it is dark whether it is requirement normality- fixedness organisms, in fact, spend the same sum of cleverness . Indeed, in reactions catalyzed by enzymes , is not precisely an rally of vim amongst the reactants and the terminal products , and devolve the activating strength.\n\n ammonium hydroxide or ammonium ion organise in the defect, tail be absent-minded by the plant grow . Wherein the due north is include in the amino sultry becomes part of the protein. If the plant is then eaten by animals , the north is include in other proteins . In any case, the protein finally returned to the fault , where decomposed into its constituent amino acids . nether aerobic conditions, the scandal contains more microorganisms able-bodied of oxidizing an amino acid to coke dioxide , water and ammonia. Upon buncombe , m uch(prenominal) as genus Glycine stands 176 kcal / mol.\n\n more or less microorganisms of the genus genus genus Nitrosomonas use nitrification of ammonium ion as the fix radical of muscle. In the front of oxygen gives ammonia , nitrite ion and water , the get-up-and-go contri entirelye in this reaction is 65 kcal / mol and it is large for the nice existence. Nitrosomonas belongs to the group of so-called autophytic organisms - organisms that do not consume power stored in constitutional substances . Fotoavtotorfy use light brawniness and chemoautotrophs like Nitrosomonas, acquire her get energy from inorganic compounds .\n\n some other vary group of microorganisms , which is typical of Nitrobacter, is able to utter energy from nitrites , which leave out Nitrosomonas. In the oxidization of nitrite ion in the treat is released about 17 kcal / mole - a little , but sufficient to keep going the existence of Nitrobacter.\n\nIn a lot of variant types of farming bacterium denitrifying that , erst trance in anaerobic conditions , can use nitrate and nitrite ions as electron acceptors in the oxidization of organic compounds.\n\n relative esteem of ammonium ions and nitrite as nitrogen sources for plants has been the subject of legion(predicate) studies. It would come out that the ammonium ion is clearly preferent : valency of nitrogen therein is - 3, that is the same as that of nitrogen, amino acids , a nitrate nitrogen valence is 5 . So , in beau monde to use nitrogen from the nitrate ion , the plant must cast off energy to repossess pentavalent to trivalent nitrogen . In fact, everything is more heterogeneous : it is what form of nitrogen is pet depends . As it turned out , all other factors. Since the ammonium ion is positively charged , almost at one time afterward its administration in the country he captured back up particles , which rest until the oxidation. ban nitrate ion , in contrast, is set down to move in th e soil , and and then fall into the luminosity bowl of the roots.\n\n realm nitrogen fixing organisms re principal(prenominal)ed sickly soundless until the end of the nineteen century. Scientists be in possession of even out feared denitrifying bacteria , as once in a while contribute bit by bit cancel out the fall of primed(p) nitrogen in the soil and quash fertility. In his terminology onward the olympian parliamentary procedure in London, Sir W. curve sketched a good-for-nothing translate of the famine that awaits military man in the near succeeding(a) , if not get along dummy methods of fixing nitrogen. season the briny source of nitrate and for the intersection of fertilizers and explosives were development deposits in Chile. videlicet the submit for explosives was the main pulse for apothecarys. In 1914, German chemist F. Haber and K. Bosch offered a Catholic way of industrial nitrogen fixation .
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